锟戒化锟絏鋰碉拷锟斤拷锟斤拷锟斤拷锟酵�

一锟斤拷锟戒化锟絏锟�锟斤拷锟斤拷锟斤拷锟侥氫化锟絏鋰★拷锟侥氾拷锟絏锟斤拷锟揭伙拷N锟斤拷色锟斤拷野锟缴拷Y(ji锟斤拷)锟斤拷锟斤拷末锟斤拷锟斤拷锟斤拷式锟斤拷H4AlLi锟斤拷锟斤拷锟斤拷37.9543锟斤拷锟斤拷锟节烴锟�锟斤拷锟斤拷锟斤拷锟斤拷锟斤拷锟斤拷锟侥氾拷呋锟�锟斤拷锟斤拷锟阶伙拷锟斤拷锟絯锟斤拷锟斤拷微锟斤拷锟斤拷锟斤拷锟斤拷锟斤拷锟斤拷锟斤拷锟杰伙拷O微锟斤拷锟节烴類和讹拷锟斤拷锟斤拷锟斤拷锟斤拷锟絚(di锟斤拷n)锟斤拷140锟斤拷锟斤拷锟斤拷锟杰讹拷(水=1)0.92锟斤拷(w锟斤拷n)锟斤拷锟皆凤拷(w锟斤拷n)锟斤拷 锟斤拷锟斤拷锟斤拷锟节干空氾拷锟斤拷锟杰凤拷(w锟斤拷n)锟斤拷锟斤拷锟斤拷锟斤拷锟斤拷锟杰筹拷锟斤拷锟斤拷锟斤拷锟斤拷锟斤拷水锟酵达拷锟絣(f锟斤拷)锟斤拷锟斤拷锟揭凤拷锟斤拷(y锟斤拷ng)锟斤拷

锟斤拷锟斤拷锟斤拷锟斤拷锟戒化锟絏鋰碉拷锟狡備方锟斤拷锟斤拷Schlesinger 锟斤拷锟斤拷锟竭夛拷锟较成凤拷锟斤拷锟戒化锟絏锟絚锟斤拷取锟饺★拷锟斤拷锟斤拷Schlesinger 锟斤拷锟絕锟斤拷锟斤拷锟斤拷锟斤拷锟斤拷锟斤拷锟斤拷锟斤拷取锟戒化锟絏鋰碉拷锟斤拷要锟斤拷锟斤拷锟斤拷

锟斤拷锟斤拷1锟斤拷Schlesinger 锟斤拷锟斤拷

锟斤拷锟斤拷1947锟斤拷Schlesinger锟斤拷Bond锟斤拷Finholt锟阶达拷锟狡得氫化锟絏鋰ｏ拷锟戒方锟斤拷锟斤拷锟斤拷浠拷锟絚锟給水锟斤拷锟饺伙拷锟絏锟斤拷锟斤拷锟斤拷锟斤拷锟組(j锟斤拷n)锟叫凤拷锟斤拷(y锟斤拷ng)锟斤拷4LiH + AlCl3 −Et2O→ LiAlH4 + 3LiCl锟紷锟斤拷(g锟斤拷)锟斤拷锟斤拷(y锟斤拷ng)一锟斤拷Q锟斤拷 Schlesinger 锟斤拷锟斤拷(y锟斤拷ng)锟斤拷锟斤拷锟斤拷(y锟斤拷ng)锟絘(ch锟斤拷n)锟斤拷锟斤拷锟斤拷锟饺伙拷锟絏計(j锟斤拷)锟斤拷锟�86%锟斤拷锟斤拷锟斤拷(y锟斤拷ng)锟絖始锟絩(sh锟斤拷)要锟斤拷锟斤拷锟斤拷锟斤拷锟戒化锟絏锟斤拷锟斤拷锟斤拷锟斤拷l(f锟斤拷)锟斤拷锟斤拷锟斤拷t锟斤拷锟斤拷(y锟斤拷ng)要锟斤拷(j锟斤拷ng)锟絭一锟斤拷锟絋锟斤拷(d锟斤拷o)锟节诧拷锟杰發(f锟斤拷)锟斤拷锟斤拷锟斤拷锟斤拷一锟斤拷锟絖始锟斤拷锟�(hu锟斤拷)锟斤拷锟斤拷锟揭碉拷锟劫讹拷锟組(j锟斤拷n)锟斤拷锟斤拷锟斤拷锟阶發(f锟斤拷)锟斤拷锟铰癸拷锟斤拷Schlesinger 锟斤拷锟叫很讹拷缺锟絚(di锟斤拷n)锟斤拷锟斤拷锟斤拷要锟斤拷锟斤拷锟絣(f锟斤拷)锟斤拷锟斤拷锟戒化锟揭拷锟斤拷^锟斤拷锟酵高度粉硷拷(x锟斤拷)锟斤拷锟斤拷要锟斤拷稀缺锟斤拷原锟较斤拷锟斤拷鋰★拷锟斤拷锟斤拷(y锟斤拷ng)锟斤拷3/4锟侥氫化锟斤拷D(zhu锟斤拷n)锟斤拷锟斤拷r(ji锟斤拷)锟斤拷锟斤拷锟饺伙拷鋰碉拷锟斤拷

锟斤拷锟斤拷2锟斤拷锟竭夛拷锟较成凤拷锟斤拷锟矫堿锟斤拷锟劫伙拷浠拷锟�锟斤拷锟絏锟斤拷锟竭夛拷锟斤拷锟节烴锟斤拷锟斤拷锟杰勶拷锟叫凤拷锟斤拷(y锟斤拷ng)锟斤拷

锟斤拷锟斤拷LiH + Al + 2H2 → LiAlH4

锟斤拷锟斤拷3锟斤拷锟缴氫化锟絏锟絚锟斤拷取锟斤拷锟斤拷锟絀(y锟斤拷)锟较筹拷锟斤拷一锟斤拷锟斤拷酶邷馗邏锟斤拷铣蓺浠拷X锟絚锟斤拷然锟斤拷锟絚锟饺伙拷锟斤拷M(j锟斤拷n)锟叫忥拷(f锟斤拷)锟街解反锟斤拷(y锟斤拷ng)锟斤拷锟紷一锟狡備方锟斤拷锟斤拷锟皆岋拷(sh锟斤拷)锟紽(xi锟斤拷n)锟戒化锟絏鋰的高產(ch锟斤拷n)锟绞ｏ拷

锟斤拷锟斤拷Na + Al + 2H2 → NaAlH4

锟斤拷锟斤拷NaAlH4 + LiCl −Et2O→ LiAlH4 + NaCl

锟斤拷锟斤拷锟斤拷锟斤拷LiCl锟缴氫化锟絏鋰碉拷锟斤拷锟斤拷液锟絕锟絍锟斤拷锟斤拷锟絊锟斤拷使锟戒化锟絏锟斤拷锟斤拷锟�锟斤拷锟紷锟矫帮拷锟斤拷1%(w/w)锟斤拷锟斤拷LiCl锟侥產(ch锟斤拷n)品锟斤拷锟斤拷锟斤拷锟侥氫化锟絏锟絚锟斤拷锟絈锟缴氫化锟絏锟揭诧拷煞锟斤拷锟�(y锟斤拷ng)锟斤拷锟斤拷锟絚锟饺伙拷鋰伙拷锟斤拷锟斤拷锟窖伙拷锟侥氾拷呋锟斤拷械臍浠嚪锟斤拷锟�(y锟斤拷ng)锟斤拷

锟斤拷锟斤拷锟戒化锟絏锟斤拷前锟缴拷锟斤拷w锟斤拷锟斤拷锟斤拷锟絀(y锟斤拷)品锟斤拷锟节猴拷锟斤拷锟絪锟絴(zh锟斤拷)锟斤拷通锟斤拷锟斤拷锟缴拷锟侥�锟斤拷锟戒化锟絏鋰匡拷锟斤拷通锟絕锟斤拷锟斤拷锟斤拷锟斤拷锟斤拷锟铰結(ji锟斤拷)锟斤拷锟斤拷锟结純锟斤拷锟斤拷锟組(j锟斤拷n)锟叫达拷規(gu锟斤拷)模锟斤拷锟结純锟斤拷锟斤拷使锟斤拷锟斤拷式锟斤拷取锟斤拷锟斤拷一锟斤拷锟斤拷f锟斤拷锟斤拷锟斤拷锟侥伙拷色锟斤拷末锟斤拷锟节合成ｏ拷锟斤拷?y锟斤拷n)锟斤拷s锟絴(zh锟斤拷)锟角無锟斤拷锟斤拷锟斤拷锟斤拷锟皆猴拷锟斤拷锟阶碉拷锟絚锟叫機(j锟斤拷)锟絘(ch锟斤拷n)锟斤拷锟斤拷x锟斤拷锟斤拷锟戒化锟絏鋰凤拷末锟斤拷锟节空氾拷锟斤拷锟斤拷燃锟斤拷锟斤拷锟斤拷K锟斤拷锟絯锟斤拷锟斤拷锟斤拷燃锟斤拷一些锟戒化锟絏鋰癸拷锟絀(y锟斤拷)品锟叫曪拷(hu锟斤拷)锟斤拷锟斤拷锟絍锟斤拷锟酵ｏ拷锟皆凤拷止锟斤拷锟斤拷锟絚锟秸氾拷锟叫碉拷水锟斤拷锟斤拷(y锟斤拷ng)锟斤拷锟斤拷锟斤拷通锟斤拷锟斤拷锟斤拷锟斤拷锟角凤拷锟斤拷锟剿拷锟斤拷洗锟斤拷锟斤拷芊锟�锟斤拷

锟斤拷锟斤拷锟斤拷锟斤拷锟戒化锟絏鋰碉拷锟斤拷途锟斤拷

锟斤拷锟斤拷1锟斤拷锟斤拷锟絫(y锟斤拷)藥锟斤拷锟斤拷锟较★拷锟絩(n锟斤拷ng)藥锟斤拷染锟较硷拷锟斤拷锟斤拷锟斤拷锟斤拷(x锟斤拷)锟叫機(j锟斤拷)锟较筹拷锟斤拷锟斤拷锟斤拷還原锟斤拷锟斤拷

锟斤拷锟斤拷2锟斤拷锟斤拷锟斤拷醛锟斤拷酮锟斤拷锟斤拷锟斤拷還原锟斤拷锟斤拷锟斤拷锟斤拷(y锟斤拷ng)锟窖的匡拷锟狡帮拷锟斤拷電筹拷锟斤拷锟斤拷锟斤拷

锟斤拷锟斤拷3锟斤拷锟斤拷锟斤拷烯锟斤拷锟斤拷锟斤拷烯锟饺讹拷烯锟絅锟桔猴拷锟斤拷锟竭伙拷锟斤拷锟斤拷锟斤拷锟組(j锟斤拷n)锟较斤拷C(j锟斤拷)械锟斤拷锟杰碉拷锟斤拷锟接勶拷锟斤拷锟斤拷鋼猴拷锟斤拷锟斤拷锟絶锟较斤拷锟�脫锟斤拷锟斤拷锟斤拷